Strain Hardening of Polymer Glasses: Effect of Entanglement Density, Temperature, and Rate
نویسندگان
چکیده
The strain hardening behavior of model polymer glasses is studied with simulations over a wide range of entanglement densities, temperatures, strain rates, and chain lengths. Entangled polymers deform affinely at scales larger than the entanglement length as assumed in entropic network models of strain hardening.The dependence of strain hardening on strain and entanglement density is also consistent with these models, but the temperature dependence has the opposite trend. The dependence on temperature, rate, and interaction strength can instead be understood as reflecting changes in the flow stress. Microscopic analysis of local rearrangements and the primitive paths between entanglements is used to test models of strain hardening. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3487–3500, 2006
منابع مشابه
Strain hardening of polymer glasses: entanglements, energetics, and plasticity.
Simulations are used to examine the microscopic origins of strain hardening in polymer glasses. While stress-strain curves for a wide range of temperature can be fit to the functional form predicted by entropic network models, many other results are fundamentally inconsistent with the physical picture underlying these models. Stresses are too large to be entropic and have the wrong trend with t...
متن کاملStrain hardening in polymer glasses: limitations of network models.
Simulations are used to examine the microscopic origins of strain hardening in polymer glasses. While traditional entropic network models can be fit to the total stress, their underlying assumptions are inconsistent with simulation results. There is a substantial energetic contribution to the stress that rises rapidly as segments between entanglements are pulled taut. The thermal component of s...
متن کاملStrain hardening in bidisperse polymer glasses: separating the roles of chain orientation and interchain entanglement.
The effects of entanglement and chain orientation on strain hardening in glassy polymers are separated by examining mixtures of chains with different lengths. Simulations show that the orientation of a molecule of a given chain length is the same in monodisperse systems and bidisperse mixtures, even when entangled and unentangled chains are mixed. In addition, the stress in mixtures is equal to...
متن کاملMolecular dynamics simulations of glassy polymers
We review recent results from computer simulation studies of polymer glasses, from chain dynamics around glass transition temperature Tg to the mechanical behaviour below Tg. These results clearly show that modern computer simulations are able to address and give clear answers to some important issues in the field, in spite of the obvious limitations in terms of length and time scales. In the p...
متن کاملAbnormal Plastic Behavior of Fine Grain Mp35n Alloy During Room Temperature Tensile Testing
In this paper, results of an investigation on the strain hardening responses of superalloy MP35N with two average grain sizes of 38 and 1 μm, during room temperature tensile testing are reported. The microstructural evolution of the deformed samples was studied using optical and transmission electron microscopy (TEM) techniques. The strain hardening behavior of the 38 μm material was rather sim...
متن کامل